Kimia Koordinasi: d3 Microstate dan Term Symbol
Tabel
d3 Microstate
-1 1/2
|
-1/2
|
+1/2
|
+11/2
|
|
+5
|
-
|
2+ 2- 1-
|
2+ 2- 1+
|
-
|
+4
|
-
|
2+ 2- 0-
|
2+ 2- 0+
|
-
|
2- 1- 1+
|
2+ 1+ 1-
|
|||
+3
|
2- 1- 0-
|
2+ 1- 0-
|
2+ 1- 0+
|
2+ 1+ 0+
|
2- 1+ 0-
|
2- 1+ 0+
|
|||
2- 1- 0+
|
2+ 2- -1+
|
|||
2- 2+ -1-
|
2+ 1+ 0-
|
|||
+2
|
2- 1- -1-
|
2+ 1- -1-
|
2+ 2- -2+
|
2+ 1+ -1+
|
2- 1- -1+
|
2- 1+ -1+
|
|||
2- 1+ -1-
|
2+ 1- -1+
|
|||
2+ 2- -2-
|
2+ 1+ -1-
|
|||
1+ 1- 0-
|
2+ 0- 0+
|
|||
2- 0+ 0-
|
1-1+ 0+
|
|||
+1
|
2- 1- -2-
|
2- 1- -2+
|
2- 1+ -2+
|
2+ 1+ -2+
|
2- 0- -1-
|
2- 1+ -2+
|
2+ 1- -2+
|
2+ 0+ -1+
|
|
2- 0- -1+
|
2+ 0- -1+
|
|||
2- 0+ -1-
|
1+1- -1+
|
|||
2+ 1- -2-
|
2-0+ -1+
|
|||
2+ 0- -1-
|
2+ 1+ -2-
|
|||
1+ 1- -1-
|
2+ 0+ -1-
|
|||
1-0+ 0-
|
1+0+0-
|
|||
0
|
2- 0- -2-
|
2+ 0- -2-
|
2+ 0+ -2-
|
2+ 0+ -2+
|
1- 0- -1-
|
2- 0+ -2-
|
2+ 0- -2+
|
1+ 0- -1+
|
|
1+ 1- -2-
|
2- 0+ -2+
|
|||
2- 0- -2+
|
1+1- -2+
|
|||
2- -1+ -1-
|
2+ -1+ -1-
|
|||
1+ 0- -1-
|
1+ 0+ -1-
|
|||
1-0+ -1-
|
1+ 0- -1+
|
|||
1-0- -1-
|
1-0+ -1+
|
|||
-1
|
1- 0- -2-
|
0+ 0- -1-
|
0+ 0- -1+
|
1+ 0+-2+
|
2--1--2-
|
2- -1- -2+
|
2- -1+ -2+
|
2+-1+-2+
|
|
2+ -1- -2-
|
2+ -1+ -2-
|
|||
1- 0- -2+
|
2+ -1- -2+
|
|||
1- -1+ -1-
|
1+ 0+ -2-
|
|||
2- -1+ -2-
|
1- 0+ -2+
|
|||
1- 0+ -2-
|
1+ 0- -2+
|
|||
1+ 0- -2-
|
1+ -1+ -1-
|
|||
-2
|
1- -1- -2-
|
1+ -1- -2-
|
1+ -1+ -2-
|
1+-1+-2+
|
1- -1- -2+
|
1+ -1- -2+
|
|||
1- -1+ -2-
|
1- -1+ -2+
|
|||
2- -2+ -2-
|
2+ -2+ -2-
|
|||
0- -1+ -1-
|
0+ -1+ -1-
|
|||
0+ 0- -2-
|
0+ 0- -2+
|
|||
-3
|
0- -1- -2-
|
0+ -1- -2-
|
0+ -1+ -2-
|
0+-1+-2+
|
0- -1- -2+
|
0- -1+ -2+
|
|||
0- -1+ -2-
|
0+ -1- -2+
|
|||
1- -2+ -2-
|
1+ -2+ -2-
|
|||
-4
|
-
|
0- -2+ -2-
|
0+ -2+ -2-
|
-
|
-1+ -1- -2-
|
-1+ -1- -2+
|
|||
-5
|
-
|
-1- -2+ -2-
|
-1+ -2+ -2-
|
-
|
Term
Symbol untuk Konfigurasi d3
ML/MS
|
-1 1/2
|
-1/2
|
+1/2
|
+11/2
|
+5
|
x
|
x
|
||
+4
|
x x
|
x x
|
||
+3
|
x
|
x x x x
|
x x x x
|
x
|
+2
|
x
|
x x x x x x
|
x x x x x x
|
x
|
+1
|
x x
|
x x x x x x x
x
|
x x x x x x x
x
|
x x
|
0
|
x x
|
x x x x x x x
x
|
x x x x x x x
x
|
x x
|
-1
|
x x
|
x x x x x x x
x
|
x x x x x x x
x
|
x x
|
-2
|
x
|
x x x x x x
|
x x x x x x
|
x
|
-3
|
x
|
x x x x
|
x x x x
|
x
|
-4
|
x x
|
x x
|
||
-5
|
x
|
x
|
Term Symbol :
4F, 4P, 2H, 2G, 2F, 2D, 2D, 2P
Ground State : 4F
Karena
4F memiliki nilai multiplisitas terbesar. Selain itu jika dibandingkan dengan
nilai multiplisitas tertinggi lainnya (4P), 4F memiliki
nilai L yang lebih besar.
Ground
state diperoleh pada nilai multiplisitas dan nilai L yang
terbesar. Sehingga Ground State pada konfigurasi d3 adalah 4F
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